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EXTENDING THE LIFE OF CONCRETE STRUCTURES USING GLYCEROL AS A NANOVISCOSITY MODIFIER: PROTECTION OF REINFORCEMENT STEEL BY REDUCING CHLORIDE TRANSPORT

Citation

Blair, Robert D.. (2017). EXTENDING THE LIFE OF CONCRETE STRUCTURES USING GLYCEROL AS A NANOVISCOSITY MODIFIER: PROTECTION OF REINFORCEMENT STEEL BY REDUCING CHLORIDE TRANSPORT. Theses and Dissertations Collection, University of Idaho Library Digital Collections. https://www.lib.uidaho.edu/digital/etd/items/blair_idaho_0089n_11079.html

Title:
EXTENDING THE LIFE OF CONCRETE STRUCTURES USING GLYCEROL AS A NANOVISCOSITY MODIFIER: PROTECTION OF REINFORCEMENT STEEL BY REDUCING CHLORIDE TRANSPORT
Author:
Blair, Robert D.
Date:
2017
Embargo Remove Date:
2018-06-12
Keywords:
Chloride Concrete Diffusion Electrochemistry Glycerol
Program:
Materials Science
Subject Category:
Materials Science
Abstract:

An emerging issue for renewable nuclear energy is correct storage of spent nuclear fuel. Current practice of long term storage of radioactive waste requires highly durable concrete containment units. The overall strength of concrete and the amount of protection it offers its rebar reinforcement is dependent upon the concrete's microstructure. If the microstructure is easily permeated by moisture, allowing chloride ion diffusion, the steel rebar is at risk of corrosion. Upon corrosion of the reinforcement steel, a concrete structures service life begins to decline.

Therefore, glycerol as a nanoscale viscosity modifier will be used to control transport phenomena in the conductive pathways. Increasing the moisture viscosity within pore pathways effectively slows diffusion of chloride ions through concrete. This study examines admixture effect on moisture transport phenomena (permeability) through the concretes conductive pathways (concrete pores). Simultaneously, glycerol admixtures effect on embedded reinforcement steel corrosion was characterized. Permeability was measured using direct measurement techniques while effect of glycerol on rebar corrosion was electrochemically analyzed.

Description:
masters, M.S., Materials Science -- University of Idaho - College of Graduate Studies, 2017
Major Professor:
Pesic, Batric
Committee:
Pesic, Batric; Raja, Krishnan; Moberly, James
Defense Date:
2017
Identifier:
Blair_idaho_0089N_11079
Type:
Text
Format Original:
PDF
Format:
application/pdf

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