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Analysis of Band-Edge Dynamics in ZnO and MgZnO Thin Films

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Canul, Amrah. (2015). Analysis of Band-Edge Dynamics in ZnO and MgZnO Thin Films. Theses and Dissertations Collection, University of Idaho Library Digital Collections. https://www.lib.uidaho.edu/digital/etd/items/canul_idaho_0089n_10762.html

Title:
Analysis of Band-Edge Dynamics in ZnO and MgZnO Thin Films
Author:
Canul, Amrah
Date:
2015
Keywords:
MgZnO Semiconductor Spectroscopy Urbach ZnO
Program:
Physics
Subject Category:
Physics
Abstract:

This work investigates the temperature dependence of electron states at the band-edge

in ZnO and Mg0.07Zn0.93O thin films.

To investigate the band-edge dynamics, we study in-gap states via temperature

dependent absorption spectroscopy in the range 77-500K. The in-gap states at the

band-edge were analyzed via the Urbach energy model, where the Urbach Energy is

a measure of the extent of states into the bandgap. In parallel, we also analyze the

temperature dependent Urbach energy via the Wasim model, which separates the

relative contributions of defect states and temperature dependent phonon modes to

the in-gap states.

It was found that the defect contribution to in-gap states at the band-edge

was significantly higher for Mg0.07Zn0.93O than in ZnO. Additionally, the phonon

contribution to in-gap states was less in Mg0.07Zn0.93O than in ZnO.

The author gratefully acknowledges the National Science Foundation and the U.S.

Department of Energy, Office of Basic Energy Science, Division of Materials Science

and Engineering under Grant No. DE-FG02-07ER46386.

Description:
masters, M.S., Physics -- University of Idaho - College of Graduate Studies, 2015
Major Professor:
Bergman, Leah
Committee:
Machleidt, Ruprecht; McCluskey, Matthew
Defense Date:
2015
Identifier:
Canul_idaho_0089N_10762
Type:
Text
Format Original:
PDF
Format:
application/pdf

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